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Page 1 of 6
Product Description: Material Safety Data Sheet
CLEAR-COATING
TYPE LLA5000 (AP1 – Aerosol Product)
UV-Protective Coating
Section 1: Manufacturer Identification
Formula # 30H003N12F
Company Phone Number: 262-251-6180
24 Hour Emergency: (800) 688-4005
Foreign Emergency: (01) (262) 236-8130 (USA
Date Printed: 04/07/06
Last Revision: 12/16/04
Manufactured to specifications for HPS,LLC.
Packaged for: (C2603)
HEMMI PAPILIO SUPPLIES LLC
NEWARK, TX 76071-3134
Section 2: Composition/Information on Ingredients
SARA 313 LISTED CARCINOGEN BY:
# Component CAS# % by WT. LISTED NTP IARC OSHA
1 METHYL ETHYL KETONE 78-93-3 30-36 Y N N N
2 ACETONE 67-64-1 20-26 N N N N
3 PROPANE 74-98-6 15-21 N N N N
4 PM ACETATE 108-65-6 5-8 N N N N
5 N-BUTANE 106-97-8 5-8 N N N N
6 ETHYL ESTER 763-69-9 3-5 N N N N
7 PLASTICIZER 85-68-7 1-3 Y N N N
Section 3: Hazards Identification
Emergency Overview: Danger! Extremely Flammable. Contents Under
Pressure.
Appearance/Odor: Liquid Spray Mist/Solvent Odor
Potential Health Effects: See Section 11 for more information.
Likely Routes of Exposure: Eye contact, skin contact, ingestion, and
inhalation Contact may cause redness, irritation, tearing, and
blurred vision Contact may dry skin causing cracks and irritation
May be harmful if swallowed
Exposure to high concentrations of vapors may cause drowsiness,
breathing difficulty, respiratory irritation, or headaches.
Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal.
Page 2 of 6
Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING
Medical Conditions Aggravated by Exposure:
Asthma and other respiratory ailments.
Target Organs: Kidney Liver Lung Brain
Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system
damage.
This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
Section 4: First Aid Measures
Eye Contact: Immediately flush eyes with water for at least 15
minutes. If irritation develops get
medical attention.
Skin Contact:Remove contaminated clothing and wash before reuse.
Wash skin with soap and water. Get
medical attention if irritation develops.
Inhalation: Move to fresh air. Contact emergency medical support if
breathing stops or is irregular.
Ingestion: DO NOT induce vomiting. Get medical attention
immediately.
Section 5: Fire Fighting Measures
Suitable Extinguishing Media: CO2 (Carbon Dioxide), dry chemical, or
water fog. Unsuitable Extinguishing Media: Water spray may be
unsuitable. However, if water is used, fog nozzles are preferable.
Water may be used to cool closed containers to prevent pressure
build-up and possible explosion when exposed to extreme
heat.
Products of Combustion: These products are carbon oxides (CO,CO2).
Protection of Firefighters: Full protective equipment including
self-contained breathing apparatus should be used.
section 6: Accidental Release Measures
Personal Precautions: Use personal protection recommended in Section
8.
Environmental Precautions: None known.
Page 3 of 6
Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000 UV-PROTECTIVE COATING
Methods of Containment: Absorb spilled liquid in suitable material.
Methods of Clean-up: Use spark-proof tools to sweep or scrape up and
containerize.
Other Information: Ventilate the area.
Section 7: Handling and Storage
Handling:
Vapors may ignite explosively. Prevent buildup of vapors; use with
adequate ventilation. Keep from sparks, heat, flame or other heat
sources. Do not smoke. Turn off pilot lights, heaters, electric
motors and other sources of ignition during use and until all vapors
are gone. Do not puncture or incinerate (burn) container.
Storage:
Store in dry well ventilated areas. above 48 degrees C (120 degrees
F).
Do not expose to heat or store at temperatures
Section 8: Exposure Controls/Personal Protection
Exposure Guidelines
# COMPONENT ACGIH TLV-STEL ACGIH TLV-TWA OSHA PEL-TWA
1 METHYL ETHYL KETONE 300 ppm 200 ppm 200 ppm
2 ACETONE 750 ppm 500 ppm 1000 ppm
3 PROPANE 1800 ppm 2500 ppm 1000 ppm
4 PM ACETATE N/E ppm N/E ppm N/E ppm
5 N-BUTANE N/E 800 ppm 800 ppm
6 ETHYL ESTER 100 ppm 50 ppm 50 ppm
7 PLASTICIZER N/E ppm 5 ppm 5 ppm
Engineering Controls: Not generally required if product is applied
in small quanti¬ties. If product is applied in larger quantities,
provide ventilation to keep air contamination below OSHA permissible
exposure limits and ACGIH TLV exposure levels.
Eye/face Protection: Wear safety glasses with side shields. Have eye
wash facilities immediately available.
Skin Protection: Chemical resistant gloves if contact is likely.
Page 4 of 6
Product Description: Material Safety Data Sheet
CLEAR-COATING (API - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING
Respiratory Protection: Use NIOSH-approved air-purifying respirator
with organic cartridge or canister if exposure cannot be controlled
within applicable limits with ventilation.
General Hygiene Considerations: Wash thoroughly after handling.
Section 9: Physical and Chemical Properties
Color: see product description
Odor: Solvent Odor
Physical State: Aerosol - Pressurized Liquid Freezing Point: Not
Established (mixture) Boiling Range: <-18 C to 177 C «0 F to 350 F)
Flash Point: <-18 C «0 F)
Evaporation Rate: Faste_ than ether
Upper Flammability Limit: Not Established (mixture) Lower
Flammability Limit: Not Established (mixture) Vapor Pressure:
Approximately 50 psig @ 10 C (70 F) Specific Gravity: 0.748 @15 C
(60 F)
Solubility (water): Negligible Percent Volatile, wt. %: 89.8
VOC Percent (CA): 67.9
MIR Number (CA): 1.198
Coating Category (CA): CLEAR COATING
Section 10: Stability and Reactivity
Stability: Stable under normal conditions.
Conditions to Avoid: Keep away from heat, sparks, and flames.
Incompatible Materials: Strong oxidizing agents.
Hazardous Decomposition Products: by fire - Carbon Dioxide and
Carbon Monoxide
Possibility of Hazardous Reactions: Will not occur.
Page 5 of 6
Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING
Section 11: Toxicological Information
# COMPONENT LDSO Oral LDSO Dermal
1 METHYL ETHYL KETONE 200 mg/kg 590 mg/kg
2 ACETONE 1000 mg/kg 2400 mg/kg
3 PROPANE 1000 mg/kg 1800 mg/kg
4 PM ACETATE 8535 mg/kg 5000 mg/kg
5 N-BUTANE N/E N/E
6 ETHYL ESTER N/E N/E
7 PLASTICIZER 20400 mg/kg 10000 mg/kg
See Section 3 for other acute effect information.
Chronic Effects: Prolonged over-exposure to solvent ingredients in
Section 2 may cause adverse effects to the liver, urinary,
cardiovascular and reproductive systems. Reports have associated the
repeated and prolonged occupational OVER¬EXPOSURE to solvents with
brain and nervous system damage. The deliberate misuse by
concentrating and inhaling the vapors may be harmful or fatal.
Carcinogenicity: See Section 2 for additional information.
Section 12: Ecological Information
No data available.
Section 13: Disposal Considerations
Do not puncture, incinerate or place container in trash compactor.
Dispose of product in accordance with Federal, State, and Local
regulations. Empty containers are 95% steel; recycle where allowed.
Page 6 of 6
Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING
Section 14: Transportation Information
US DOT (Ground)
Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
US DOT (Air)
Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D-AIR
lATA (Domestic Air)
CONSUMER COMMODITY, ID 8000, CLASS 9, MISCELLANEOUS LABEL, Packing
Instruction: 910.
lATA (International Air)
Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.; Class: 2.1;
UN1950; Packing Instruction: Y203; Authorization: LTD. QTY.;
FLAMMABLE GAS label required on box.
IMDG (Water)
Proper Shipping Name: AEROSOL PRODUCT, LTD QTY, IMDG Class 2, Page
2102, UN1950, Packing Group II, Marine Pollutant: Yes.
Section 15: Regulatory Information
International Chemical Inventory
TSCA: United States The components of this product are listed on the
TSCA inventory.
DSL/NDSL: Canada The components of this product are listed on the
DSL inventory.
AICS: Australia The components of this product are listed on the
AICS inventory.
Section 313 Toxic Chemicals
See section 2. Chemicals marked with a "Y" are subject to the
SARA reporting requirements under 40 cfr 372.45(c) (5).
*California Safe Drinking Water and Toxic Enforcement Act of 1986
(proposition 65)
This product contains chemicals known to the state of California to
cause cancer
and birth defects or other reproductive harm.
Section 16: Other Information
HMIS: Hazardous Material Identification System
Health – 2 Fire – 4 Reactivity - 1
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 =
severe hazard, 4 = extreme hazard
This MSDS is based on information believed to be reliable and
accurate. Because of changing reporting requirements and other
variables it is impossible to guarantee
the accuracy of the information contained in this document. It is
the responsi¬bility of the user to determine proper personal
protection based on the actual condition of use and to comply with
all Federal, State and Local laws and regulations.
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